Optically Active Cyclic Dipeptide Carrying 9-Anthryl Groups
نویسندگان
چکیده
منابع مشابه
4-(9-Anthryl)-2-methylbutyn-2-ol
There are two mol-ecules in the asymmetric unit of the title compound, C(19)H(16)O. Neighbouring mol-ecules are linked through O-H⋯O hydrogen bonds into an R(4) (4)(8) ring motif. There are also C-H⋯π hydrogen and π-π inter-actions. The mol-ecules are either parallel to each other or are inclined at an angle of 12.5 (1)°.
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A green chemistry-based highly regioselective synthesis of ethyl (9-anthryl)glyoxylate was achieved by solvent-free Friedel-Crafts reaction at r. t. Several derivatives of ethyl (9-anthryl)glyoxylate were also synthesized. Ethyl (9-anthryl)hydroxyacetate was obtained almost quantitatively by reduction of ethyl (9-anthryl)glyoxylate with NaBH4, and (9-anthryl)methoxyacetic acid was prepared by m...
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ژورنال
عنوان ژورنال: Bulletin of the Chemical Society of Japan
سال: 1986
ISSN: 0009-2673,1348-0634
DOI: 10.1246/bcsj.59.3175